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中文名称英文名称CAS 编号规格目录价所属品牌订货号
苄基三苯基氯化膦Benzyltriphenylphosphonium chloride1100-88-525G¥270.00ALDRICHB32807
苄基三苯基氯化膦Benzyltriphenylphosphonium chloride1100-88-5100G¥810.00ALDRICHB32807
苄基三苯基氯化膦Benzyltriphenylphosphonium chloride1100-88-5500G¥3,550.00ALDRICHB32807
品牌ALDRICH
产品名称 苄基三苯基氯化膦 : Benzyltriphenylphosphonium chloride ——【产品编号:ALDRICH-B32807】
CAS编号1100-88-5
别名苄基三苯基氯化磷,BPP,BTPPC, NSC 116712, Triphenyl(phenylmethyl)phosphonium chloride
级别科学级
纯度&分析99%
TipsBSZH品质推荐:SIGMA-ALDRICH 进口高等级基础试剂,多重遴选,国际标准严苛测试,全球化学产品质量标杆,满足用户更高应用要求。 使用SIGMA-ALDRICH品质优异、表现卓越的试剂类产品,将有助于使您的研究项目更早获益。
分子式C6H5CH2P(Cl)(C6H5)3
分子量388.87
储存条件常温避光保存。
性质

Application

Crosslinking agent for tube-like natural halloysite / fluorelastomer nanocomposites1

Reactant for synthesis of:
• Platinum chloro tetrazole complexes via azidation2
• Trans-stilbenes and cinnamates via Wittig olefination3
• Achiral N-hydroxyformamide inhibitors of ADAM-TS4 and ADAM-TS5 for osteoarthritis treatment4
• Pentiptycenes for use as light-driven molecular brakes5

Reactant for formation of archipelago structures for formation of petroleum asphaltenes6

 性质

Related Categories C-C Bond Formation, Chemical Synthesis, Olefination, Synthetic Reagents, Wittig Reagents
assay 99%
mp ≥300 °C(lit.)
原产地美国
描述

产品性状:本品溶于水,溶于氯仿,微溶于低分子量的脂肪族醇。热分解温度>323℃,略带苄基味。与双酚AF配合用于氟橡胶的硫化剂。

供货状态True
参考文献

1. S. Rooj, et al., Eur. Polymer J. 47, 1746-1755, (2011)

2. E. A. Popova, et al., Inorganica Chim. Acta 375, 242-247, (2011)

3. Amine- and sulfonamide-promoted wittig olefination reactions in water. J. McNulty and D. McLeod, Chem. Eur. J. 17, 8794-8798, (2011)

4. Orally active achiral N-hydroxyformamide inhibitors of ADAM-TS4 (aggrecanase-1) and ADAM-TS5 (aggrecanase-2) for the treatment of osteoarthritis. C. De Savi, et al., Bioorg. Med. Chem. Lett. 21, 3301-3306, (2011)

5. Pentiptycene-derived light-driven molecular brakes: substituent effects of the brake component. W. Sun, et al., Chem. Eur. J. 16, 11594-11604, (2010)

6. A. H. Alshareef, et al., Energy and Fuels 25, 2130-2136, (2011)

Beil. 16,IV,994

Fieser 5,30

Corp MSDS 1 (1), 405:B / FT-IR 2 (2), 3335:A / FT-IR 1 (2), 547:D / FT-NMR 1 (2), 1675:A / IR-Spectra (2), 1031:G / IR-Spectra (3), 1184:G / NMR-Reference 2 (2), 883:D / RegBook 1 (2), 2277:E / Structure Index 1, 356:D:5

类型BSZH 高等级基础试剂
安全信息
符号 GHS06
信号词 Danger
危险声明 H300
警示性声明 P264-P301 + P310
个人防护装备 Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges
危害码 (欧洲) T
风险声明 (欧洲) 25
安全声明 (欧洲) 26-36/37/39-45
RIDADR UN 2811 6.1/PG 2
WGK德国 3
RTECS TA2416500
燃点(华氏) 572 °F
燃点(摄氏) 300 °C