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三乙基胺Triethylamine121-44-8100MLSIGMA90335
三乙基胺Triethylamine121-44-81LSIGMA90335
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品牌SIGMA
产品名称 三乙基胺 ： Triethylamine ——【产品编号：SIGMA-90335】
CAS编号121-44-8
别名流动相：三乙胺
级别生化级
纯度&分析BioUltra, ≥99.5% (GC)
Tips酸性、碱性和中性药物 RP-HPLC 分离中的流动相改性剂。通过抑制拖尾提高氨基酸和氨基​酸酰胺的 HPLC 分离度。
分子式(C2H5)3N
分子量101.19
储存条件2-8 °C 冷藏保存。
性质
vapor density 3.5 (vs air)
vapor pressure 51.75 mmHg ( 20 °C)
product line BioUltra
assay ≥99.5% (GC)
autoignition temp. 593 °F
expl. lim. 8 %
impurities insoluble matter, passes filter test
  ≤0.5% water
evapn. residue ≤0.003%
refractive index n20/D 1.401(lit.)
bp 88.8 °C(lit.)
mp −115 °C(lit.)
density 0.726 g/mL at 25 °C(lit.)
cation traces Al: ≤0.2 mg/kg
  Ba: ≤0.1 mg/kg
  Bi: ≤0.1 mg/kg
  Ca: ≤0.5 mg/kg
  Cd: ≤0.05 mg/kg
  Co: ≤0.02 mg/kg
  Cr: ≤0.02 mg/kg
  Cu: ≤0.02 mg/kg
  Fe: ≤0.1 mg/kg
  K: ≤0.5 mg/kg
  Li: ≤0.1 mg/kg
  Mg: ≤0.1 mg/kg
  Mn: ≤0.02 mg/kg
  Mo: ≤0.02 mg/kg
  Na: ≤0.5 mg/kg
  Ni: ≤0.02 mg/kg
  Pb: ≤0.1 mg/kg
  Sr: ≤0.1 mg/kg
  Zn: ≤0.1 mg/kg
abs. absorption/278 nm cut-off
storage temp. 2-8°C
原产地美国
描述

Application

酸性、碱性和中性药物 RP-HPLC 分离中的流动相改性剂。通过抑制拖尾提高氨基酸和氨基​酸酰胺的 HPLC 分离度。

Triethylamine, a mobile-phase modifier in the RP-HPLC separation of acidic, basic and neutral molecules, improves the resolution of amino acids and amino acid amides by HPLC by suppressing tailing and the stability of drugs and other compounds.

Other Notes

Component of volatile buffer system in ion-exchange HPLC of oligonucleotides1
供货状态True
参考文献

1. Use of a volatile buffer system in ion-exchange high-performance liquid chromatography of oligonucleotides. J.M. Munholland et al. Anal. Biochem. 178, 320, (1989)

Development and Validation of RP-HPLC Method for Simultaneous Determination of Granisetron and Dexamethasone. Heda AA, Kathiriya JM, Gadade DD, Puranik PK. Indian J. Pharm. Sci. 73, 696-699, (2011)

Stability indicating HPLC method for the simultaneous determination of moxifloxacin and prednisolone in pharmaceutical formulations. Razzaq SN, Khan IU, Mariam I, Razzaq SS. Chem. Cent. J. 6, 94, (2012)

General reversed-phase high-performance liquid chromatographic method for the separation of drugs using triethylamine as a competing base. R.W. Roos, C.A. LauCam J. Chromatogr. A 370, 403, (1986)

Determination of the enantiomers of alpha-amino acids and alpha-amino acid amides by high-performance liquid chromatography with a chiral mobile phase. A. Duchateau J. Chromatogr. A 461, 419, (1989)

Stability-Indicating RP-HPLC Method for the Simultaneous Determination of Escitalopram Oxalate and Clonazepam. Kakde RB, Satone DD, Gadapayale KK, Kakde MG. J. Chromatogr. Sci., (2012)

High-throughput carotenoid profiling using multivariate curve resolution. Wehrens R, Carvalho E, Masuero D, et al. Anal. Bioanal. Chem, (2012)

Merck 14,9666

Beil. 4,IV,322

FT-IR 1 (1), 300:A / FT-NMR 1 (1), 481:B
类型流动相
安全信息
符号 GHS02GHS05GHS07 
信号词 Danger
危险声明 H225-H302-H312-H314-H332
警示性声明 P210-P280-P305 + P351 + P338-P310
个人防护装备 Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
危害码 (欧洲) F,C
风险声明 (欧洲) 11-20/21/22-35
安全声明 (欧洲) 3-16-26-29-36/37/39-45
RIDADR UN 1296 3/PG 2
WGK德国 1
RTECS YE0175000
燃点（华氏） 5 °F
燃点（摄氏） -15 °C